Herbicide Mode of Action Table

HERBICIDE MODE OF ACTION TABLE

High resistance risk 

Group 1 

Inhibition of acetyl co-enzyme A carboxylase (ACC’ase inhibitors) 

Chemical family  Active constituent (first registered trade name) 
Aryloxyphenoxy-propionates (FOPs)  clodinafop (Topik®), cyhalofop (Agixa®*, Barnstorm®), diclofop (Cheetah® Gold* Decision®*, Hoegrass®), fenoxaprop (Cheetah®, Gold*, Wildcat®), fluazifop (Fusilade®, RoundupFNG Weedkiller®*), haloxyfop (Verdict®), propaquizafop (Shogun®), quizalofop (Targa®) 
Cyclohexanediones (DIMs)  butroxydim (Factor®*), clethodim (Select®, Zero Triple Action Garden Weedkiller®*), profoxydim (Aura®), sethoxydim (Cheetah® Gold*, Decision®*), tralkoxydim (Achieve®) 
Phenylpyrazoles (DENs)  pinoxaden (Axial®) 

 

Group 2 

Inhibition of acetolactate synthase (ALS inhibitors), acetohydroxyacid synthase (AHAS) 

Chemical family  Active constituent (first registered trade name) 
Imidazolinones (IMIs)  imazamox (Intervix®*, Raptor®), imazapic (Bobcat I-Maxx®*, Flame®, Midas®*, OnDuty®*), imazapyr (Arsenal Xpress®*, Intervix®*, Lightning®*, Midas®* OnDuty®*, Roundup PNG Weedkiller®*), imazethapyr (Lightning®*, Spinnaker®) 
Pyrimidinyl–thio-benzoates  bispyribac (Nominee®), pyrithiobac (Staple®) 
Sulfonylureas (SUs)  azimsulfuron (Gulliver®), bensulfuron (Londax®), chlorsulfuron (Glean®), ethoxysulfuron (Hero®), flazasulfuron (Katana®), foramsulfuron (Tribute®), halosulfuron (Sempra®), iodosulfuron (Hussar®), mesosulfuron (Atlantis®), metsulfuron (Ally®, , Stinger®*, Trounce®*, Ultimate Brushweed®* Herbicide), prosulfuron (Casper®*), rimsulfuron (Titus®), sulfometuron (Oust®, Eucmix Pre Plant®*, Trimac Plus®*), sulfosulfuron (Monza®), , triasulfuron (Logran®, Logran® B-Power®*), tribenuron (Express®), trifloxysulfuron (Envoke®, Krismat®*) 
Triazolopyrimidines-Type 1   florasulam (Crest®*, Gangster®*, Paradigm®*, Vortex®*, XPand®*), flumetsulam (Broadstrike®, Thistrol® Gold*), metosulam (Eclipse®) 
Triazolopyrimidines-Type 2  pyroxsulam (Crusader® Rexade®*) 

* This product contains more than one active constituent. 

 

Moderate resistance risk 

Group 3 

Inhibition of microtubule assembly – α-tubulin 

Chemical family  Active constituent (first registered trade name) 
   
Dinitroanilines: (DNAs)  oryzalin (Rout®*, Surflan®), pendimethalin (Freehand*®, OH2 Ornamental Herbicide®*, Stomp®), prodiamine (Barricade®), trifluralin (Bolta Duo®*, Jetti Duo®*, Treflan®) 
Pyridines  dithiopyr (Dimension®) 

 

Group 4 

Disruptors of plant cell growth (Auxin mimics) 

Chemical family  Active constituent (first registered trade name) 
Benzoates   dicamba (Banvel®, Banvel M®*, Barrel®*, Casper®*, Lawnweeder plus®*, Lawn weedkiller*, Mecoban®, Methar Tri-Kombi®*, Nuturf Millennium®*, Sandoban®*) 
Phenoxy-carboxylates  

(Phenoxys) 

2,4-D (Actril DS®*, Amicide®, Fallow Boss Tordon®*, Methar Tri-Kombi®*, Pyresta®*, Vortex®*), 2,4-DB (Trifolamine®), dichlorprop (Lantana 600®), MCPA (Agtryne® MA*, Banvel M®*, Barrel®*, Basagran® M60*, Buctril® MA*, Buffalo Pro Weedkiller®*, Condor*®, Flight®*, Lawnweeder plus®*, Lawn Weedkiller*, Midas®*, Paragon®*, Precept®*, Quadrant®*, Silverado®*, Spearhead®*, Thistrol Gold*®, Tigrex®*, Tordon 242®*, Triathlon®*, Zero Triple Action Garden Weedkiller ®*), MCPB (Legumine®, Thistrol Gold*®), mecoprop  (Mecoban®, Mecopropamine®, Methar TriKombi®*, Multiweed®*) 
Pyridine carboxylates  

(Pyridines) 

Aminocyclopyrachlor (Method®), aminopyralid (Fallow Boss Tordon®*, ForageMax®*, Grazon Extra®*, Grindstone®, Hotshot®*, Stinger®*, Vigilant II®*), clopyralid (Lontrel®, Nuturf Millennium®*, Spearhead®*, Trimac Plus®*, Velmac Plus®*) , florpyrauxifen (Agixa®*, Ubeniq®), halauxifen (ForageMax®*, Paradigm®*, Pixxaro®*, Rexade®*), picloram (Fallow Boss Tordon®*, Grazon Extra®*, Tordon®, Tordon 242®*, Tordon Regrowth Master®*, Trinoc®*, Vigilant II®*),  
Quinoline-carboxylates   quinclorac (Drive®) 
Pyridyloxy-carboxylates  fluroxypyr (Crest®*, Hotshot®*, Monsoon®*, Pixxaro®*,Roundup FNG Weedkiller®*, Roundup PNG Weedkiller®*, Starane®), triclopyr (Garlon®, Grazon Extra®*, Tordon Regrowth Master®*, Tough Roundup® Weedkiller*, Ultimate Brushweed®* Herbicide)  

 

 

Group 5 

Inhibition of photosynthesis at photosystem II – D1 Serine 264 binders (and other non-histidine binders) (PS II Serine 264 inhibitors ) 

Chemical family  Active constituent (first registered trade name) 
Amides  propanil (Stam®) 
Phenylcarbamates  phenmedipham (Betanal®) 
Pyridazinones  chloridazon (Pyramin®) 
Triazines  ametryn (Amigan®*, Gesapax® Combi*, Krismat®, Primatol Z®), atrazine (Gesapax® Combi*, Gesaprim®, Primextra® Gold*), cyanazine (Bladex®), prometryn (Bandit®*, Cotogard®*, Gesagard®), propazine (Agaprop®), simazine (Brunnings RTU Path Weeder®*, Gesatop®, Bantox®*, Yates Once A Year Path Weeder®*), terbuthylazine (Effigy*®, Firestorm®*, Palmero TX®*, Terbyne®), terbutryn (Agtryne® MA*, Amigan®*, Igran®) 
Triazinones  amicarbazone (Amitron®*) hexazinone (Bobcat I-Maxx®*, Velmac Plus®*, Velpar® K4*, Velpar® L), metribuzin (Aptitude®*, Sencor®) 
Uracils  bromacil (Hyvar®, Krovar®*), terbacil (Eucmix Pre Plant®*, Sinbar®, Trimac Plus®*) 
Ureas  diuron (Karmex®, Krovar®*, Velpar® K4*), fluometuron (Bandit®*, Cotogard®*, Cotoran®), linuron (Afalon®), metobromuron (Soleto®), methabenzthiazuron (Tribunil®), siduron (Tupersan®), tebuthiuron (Graslan®) 

 

Group 6 

Inhibition of photosynthesis at photosystem II – D1 Histadine 215 binders (PS II Histadine 215 inhibitors) 

Chemical family  Active constituent (first registered trade name) 
Benzothiadiazinones  bentazone (Basagran®, Basagran® M60*, Lawnweeder Plus®*) 
Nitriles  bromoxynil (Barrel®*, Buctril®, Buctril® MA*, Buffalo Pro Weedkiller®*, Eliminar C®*, Flight®*, Jaguar®*, Monsoon®*, Quadrant®*, Talinor®*, Triathlon®*, Velocity®*), ioxynil (Actril® DS*, Totril®) 

 

Group 9 

Inhibition of 5-enolpyruvyl shikimate-3 phosphate synthase (EPSP inhibition) 

Chemical family  Active constituent (first registered trade name) 
Glycines  glyphosate (Arsenal Xpress®*, Bantox*, Broadway®*, Firestorm®*, Illico®*, Resolva®*, Roundup®, Sandoban*®, Tough Roundup® Weedkiller*, Trounce®*,  Pathweeder®*) 

 

 

Group 10 

Inhibition of glutamine synthetase 

Chemical family  Active constituent (first registered trade name) 
Phosphinic acids  glufosinate-ammonium (Basta®, Hellcat®*, Liberty®), glufosinate-p-ammonium (Basta® Ultra, Liberty® Ultra) 

 

Group 12 

Inhibition of carotenoid biosynthesis at the phytoene desaturase step (PDS inhibitors) 

Chemical family  Active constituent (first registered trade name) 
N-Phenyl heterocycles  norflurazon (Solicam®) 
Phenyl-ethers  diflufenican (Brodal®, Gangster®*, Infinity Ultra®*, Jaguar®*, Mateno® Complete*, Quadrant®*, Spearhead®*, Tigrex®*, Triathlon®*, Pathweeder®*), picolinafen (Eliminar C®*, Flight®*, Paragon®*, Quadrant®*, Sniper®) 

 

Group 13 

Inhibition of deoxy-D-xyulose phosphate synthase (DOXP inhibitors) 

Chemical family  Active constituent (first registered trade name) 
Isoxazolidinones  bixlozone (Overwatch®), clomazone (Altiplano®*, Command®) 

 

Group 14 

Inhibition of protoporphyrinogen oxidase (PPO inhibitors) 

Chemical family  Active constituent (first registered trade name) 
Diphenyl ethers  acifluorfen (Blazer®), fomesafen (Reflex®), oxyfluorfen (Goal®, OH2 Ornamental Herbicide®*, Rout®, Pathweeder®) 
N-Phenyl-oxadiazolones  oxadiargyl (Raft®), oxadiazon (Ronstar®) 
Phenylpyrazoles  pyraflufen (Condor*®, Ecopar®, Pyresta®*) 
N-Phenyl-imides  butafenacil (B-Power®*, Logran® B-Power®*, Resolva®*), flumioxazin (Valor®, Terrain®), saflufenacil (Sharpen®, Voraxor*®), tiafenacil (Terrad’Or®), trifludimoxazin (Voraxor*®) 
N-Phenyl-triazolinones  carfentrazone (Affinity®, Aptitude®*, Broadway®, Buffalo Pro Weedkiller®*, Hellcat®*, Silverado®*) 

 

 

Group 15 

Inhibition of very long chain fatty acid synthesis (VLCFA inhibitors) 

Chemical family  Active constituent (first registered trade name) 
α-Chloroacetamides  dimethenamid-p(Freehand*, Frontier®-P, Outlook ®), metazachlor (Butisan®), metolachlor (Boxer® Gold*, Dual® Gold, Primextra® Gold*), propachlor (Prothal®*, Ramrod®) 
Benzofurans  ethofumesate (Tramat®) 
Isoxazolines  pyroxasulfone (Mateno® Complete*, Sakura®) 
Thiocarbamates  EPTC (Eptam®), molinate (Ordram®), pebulate (Tillam®), prosulfocarb (Arcade®, Bolta Duo®*, Boxer® Gold*, Diablo Duo®*), thiobencarb (Saturn®), tri-allate (Avadex®, Diablo Duo®*, Jetti Duo®*), vernolate (Vernam®) 

 

Group 18 

Inhibition of dihydropteroate synthase (DHP inhibitors) 

Chemical family  Active constituent (first registered trade name) 
Carbamates  asulam (Asulox®) 

 

Group 19 

Inhibition of auxin transport (ATIs) 

Chemical family  Active constituent (first registered trade name) 
Aryl-carboxylates  naptalam (Alanap-L®) 

 

Group 22 

Inhibition of photosynthesis at photosystem I via electron diversion (PSI electron diversion) 

Chemical family  Active constituent (first registered trade name) 
Pyridiniums  diquat (Reglone®, Spray Seed®*), paraquat (Alliance®*, Gramoxone®, Spray Seed®*) 

 

Group 23 

Microtubule interference – unclear site of action 

Chemical family  Active constituent (first registered trade name) 
Benzamides  propyzamide (Effigy®*, Kerb®) 
Carbamates  carbetamide (Carbetamex®, Ultro®), chlorpropham (Chlorpropham®) 

 

 

Group 27 

Inhibition of 4-hydroxyphenyl-pyruvate dioxygenase (HPPD inhibitors) 

Chemical family  Active constituent (first registered trade name) 
Isoxazoles  isoxaflutole (Balance® Palmero TX®*) 
Pyrazoles  benzofenap (Taipan®), pyrasulfotole (Galaxy®, Infinity Ultra®*, Precept®*, Velocity®*), topramezone (Frequency®) 
Triketones  bicyclopyrone (Talinor®*), mesotrione (Callisto®) 

 

Group 29 

Inhibition of cellulose biosynthesis 

Chemical family  Active constituent (first registered trade name) 
Alkylazines  indaziflam (Specticle®) 
Benzamides  isoxaben (Gallery®, X-Pand®*) 
Nitriles  dichlobenil (Casoron®) 

 

Group 30 

Inhibition of fatty acid thioesterase  

Chemical family  Active constituent (first registered trade name) 
Benzyl ether  cinmethylin (Luximax®), methiozolin (PoaCure Turf®)  

 

Group 31 

Inhibition of serine-threonine protein phosphatase (STPP inhibitors) 

Chemical family  Active constituent (first registered trade name) 
Unknown  endothal (Endothal®) 

 

Group 32 

Inhibition of solanesyl diphosphate synthase 

Chemical family  Active constituent (first registered trade name) 
Diphenyl ether  aclonifen (Mateno® Complete*) 

 

Group 34 

Inhibition of lycopene cyclase  

Chemical family  Active constituent (first registered trade name) 
Triazoles  amitrole (Alliance®*, Amitrole®, RTU Pathweeder®*, Illico®*, Firestorm®*, Onceyear Pathweeder®*) 

Group 0 

Herbicides with unknown mode of action 

Chemical family  Active constituent (first registered trade name) 
Arylaminopropionic acids  flamprop (Mataven® L) 
Acetamides  napropamide (Altiplano®*, Devrinol®) 
Organoarsenicals  DSMA (disodium methylarsonate) (Methar®, Trinoc®*), MSMA (monosodium methylarsonate) (Daconate®) 
Fatty acids  Pelargonic acid (Nonanoic acid) Roundup FNG Weedkiller®*, Roundup PNG Weedkiller®*, Slasher®, Zero Triple Action Garden Weedkiller®*) 
Chlorocarbonic acids  dalapon (Dalapon®, Onceyear Pathweeder®*, flupropanate (Frenock®) 
Phosphorodithioates  bensulide (Prefar®) 

* This product contains more than one active constituent 

Notes 

  1. List of approved active constituents in each “Group” and, for ease of identification, at the discretion of the Expert Committee on Herbicide Resistance. 
  2. The trade name of the first registered product or successor. 
  3. Refer to the APVMA website (www.apvma.gov.au) to obtain a complete list of registered products from the PUBCRIS database. 

URL: https://croplife.org.au/resources/programs/resistance-management/herbicide-moa-table-4/
Content last updated: July 22, 2026

CropLife Australia’s Resistance Management Strategies provide a guide for crop protection product rotation through product groups. The strategies are a useful tool that supports farmers’ adoption of resistance management. All crop protection products must be handled and applied strictly as specified on the product label or APVMA permits.

These Resistance Management Strategies do not replace product labels. They are a guide only and do not endorse particular products, groups of products or cultural methods in terms of their performance. It is important to check with the Australian regulator’s (APVMA) product database for contemporary information on products and active constituents. The database can be sourced through www.apvma.gov.au

The information given in this strategy is provided in good faith and without any liability for loss or damage suffered as a result of its application and use. Advice given in this strategy is valid as at 22 July 2026. All previous versions of this strategy are now invalid.